Login   |   Create New Account sales@aaronchem.com

Home > Products> 135139-00-3
135139-00-3

(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene

Catalog#: AR003D2F  |   CAS#: 135139-00-3  |   MDL#: MFCD01630821  |   MF: C52H48P2  |   MW: 734.8850

Packsize Purity Price Availability Quantity
100mg 95% $6.00 Global Stock Buy Now Add To Cart
250mg 95% $12.00 Global Stock Buy Now Add To Cart
1g 95% $31.00 Global Stock Buy Now Add To Cart
2.5g 95% $76.00 Global Stock Buy Now Add To Cart
5g 95% $144.00 Global Stock Buy Now Add To Cart
10g 95% $269.00 Global Stock Buy Now Add To Cart
25g 95% $532.00 Global Stock Buy Now Add To Cart
  • Description
  • Application
  • Related Products
  • Featured Products
  • Safety Information
Catalog Number AR003D2F
Chemical Name (R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene
CAS Number 135139-00-3
Molecular Formula C52H48P2
Molecular Weight 734.8850
MDL Number MFCD01630821
SMILES Cc1cc(C)cc(c1)P(c1ccc2c(c1c1c(ccc3c1cccc3)P(c1cc(C)cc(c1)C)c1cc(C)cc(c1)C)cccc2)c1cc(C)cc(c1)C

(S)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, often referred to as $name$, is a versatile chiral ligand commonly used in asymmetric catalysis. In chemical synthesis, this compound plays a crucial role in promoting a variety of reactions with high enantioselectivity.One key application of (S)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl is in transition metal-catalyzed asymmetric hydrogenation reactions. By coordinating with transition metal catalysts, this ligand can facilitate the reduction of prochiral substrates to produce chiral molecules with excellent stereoselectivity. This ability to control the orientation of bond formation makes (S)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl a valuable tool in the synthesis of pharmaceutical intermediates, natural products, and fine chemicals.Moreover, (S)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl is also employed in other asymmetric transformations such as asymmetric allylic substitutions, nucleophilic additions to carbonyl compounds, and cycloaddition reactions. Its presence can enhance reaction efficiency, increase product yields, and provide access to enantiomerically enriched compounds that are crucial in drug development and material science.Overall, (S)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl stands as a vital component in modern chemical synthesis, enabling the creation of complex molecules with high levels of stereocontrol and paving the way for the production of valuable compounds with diverse applications.
13885-09-1

Phosphine, [1,1'-biphenyl]-2-yldiphenyl-

13885-09-1

132071-87-5

Ruthenium, [(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]dichloro-, (SP-4-2)- (9CI)

132071-87-5

98327-87-8

2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene

98327-87-8

261948-85-0

Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-

261948-85-0

84783-64-2

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl

84783-64-2

135139-00-3

(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene

135139-00-3

99646-28-3

Phosphine, (1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-

99646-28-3

76189-56-5

Phosphine, (1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenyl-

76189-56-5

139115-90-5

Ethanol, 2-(2-azidoethoxy)-

139115-90-5

$76.00/250mg, $105.00/500mg,

346603-63-2

Methyl 2-methyl-3-(trifluoromethyl)benzoate

346603-63-2

$5.00/250mg, $7.00/1g, $24.00/5g, $43.00/10g, $104.00/25g, $201.00/50g, $399.00/100g,

185-72-8

1,6-Dioxaspiro[2.5]octane

185-72-8

$14.00/100mg, $26.00/250mg, $52.00/1g, $170.00/5g, $312.00/10g, $606.00/25g, $1,108.00/50g, $2,043.00/100g,

337915-79-4

1,2-BENZENEDIAMINE, 4-BROMO-N2-METHYL-

337915-79-4

$5.00/100mg, $7.00/250mg, $18.00/1g, $88.00/5g, $174.00/10g, $381.00/25g, $727.00/50g, $1,385.00/100g,

1246549-62-1

Quinoline, 7-bromo-3-chloro-

1246549-62-1

$91.00/100mg, $146.00/250mg, $260.00/1g, $779.00/5g, $1,385.00/10g,

2621932-49-6

2-(8-Fluoronaphthalen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2621932-49-6

$116.00/100mg, $217.00/250mg, $520.00/1g, $1,558.00/5g,

GHS Pictogram
Signal Word Warning
UN# -
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305+P351+P338
Class -
Packing Group -

Home| Products| Terms & Conditions| Ordering & Shipping| Company| Contact us

© 2019 Aaron Chemicals LLC. All Rights Reserved.